George Clooney, Amal Alamuddin hold Venice rehearsal dinner

-ALLCOUNTRYSplash News/Splash News George Clooney’s fiancée Amal Alamuddin smiles in Venice, surrounded by family, the night before their wedding.

Like conquers all — even the heart of confirmed bachelor George Clooney.

Hollywood’s most eligible leading man beamed alongside his glowing bride Amal Alamuddin in Venice Friday as the couple welcomed family and friends on the eve of their wedding.

The legendary lady-killer appeared thrilled to be surrendering his release status as he raised a glass with best buddies Matt Damon, Rande Gerber and several other celebrities.

The 53-year-ancient seemed overjoyed as he watched Alamuddin gingerly step on the teach a luxury mahogany gondola next to his.

The boat was apparently almost as tipsy as the the men. Clooney, holding a nearly empty glass of spirits, appeared to shout some information to Alamuddin as she carefully navigated her way in a stunning red gown that accentuated her gorgeous dark hair and dramatic, red-lipped smile.

USA ONLYXPOS/Xposure/AKM-GSI Clooney raises a glass on the teach a gondola at the luxurious Hotel Cipriani — on a private island in Venice’s lagoon — where everyone reportedly gathered for the couple’s dry run dinner Friday.

Alamuddin, 36, a British-Lebanese human rights lawyer, was joined by her smiling mother and sister and other friends on the boat.

The setting was the luxurious Hotel Cipriani — on a private island in Venice’s lagoon — where everyone reportedly gathered for the dry run dinner.

Alamuddin is stunning in red on the eve of her wedding.Splash News Alamuddin is stunning in red on the eve of her wedding.

Clooney, whose quaint like life has been tabloid fodder for decades, had vowed never to marry again after a disastrous trip down the aisle as a young man. His first marriage — to actress Talia Balsam — finished in divorce four years later in 1993.

He was so avowedly anti-marriage that he once bet actress Michelle Pfeiffer $ 100,000 that he would never get hitched again.

USA ONLYXPOS/Xposure/AKM-GSI Alamuddin, 36, a British-Lebanese human rights lawyer, is joined by her smiling mother and sister and other friends.

Clooney-watchers were mesmerized — and many female hearts broken — when he announced his engagement to the striking and brainy Alamuddin five months ago.

It’s not yet clear if Pfeiffer was among the mad dash of Hollywood heavy-hitters who flew to Venice Friday ahead of the dry run dinner.

-ALLCOUNTRYSplash News Clooney is surrounded by buddies as he and his bride float on matching gondolas.

Matt Damon, a member of Clooney’s “Ocean’s Eleven” mob, was among the first to arrive with his wife, Luciana.

There was no sight of Mr. and Mrs. Jolie-Pitt in the crowd — but Angelina and Brad were both expected to attend the glitz-filled wedding ceremony Saturday.

Anna Wintour arrives in Venice on Friday ahead of the star-studded nuptials. Andrew Medichini/AP

Anna Wintour arrives in Venice on Friday ahead of the star-studded nuptials.

Luigi Costantini/AP

Matt Damon, Clooney’s ‘Ocean’s Eleven’ co-star, arrives in Italy.

Luigi Costantini/AP Clooney (right) is flanked by Alamuddin, Cindy Crawford (bottom right) and her husband Rande Gerber.

Additional well-known faces glimpsed Friday amid the gorgeous Byzantine and Renaissance architecture of Venice included Clooney’s cousin Miguel Ferrer, actress Ellen Barkin and Rage editor Anna Wintour.

While some of the merriment were plotted at the Hotel Cipriani, the wedding was reportedly set for the opulent seven-star Hotel Aman on Saturday. Formerly a Renaissance palace, the Aman’s 24 rooms have been fully booked for this weekend months in advance.

Venice city officials have said a 50-yard length of pedestrian way along the Grand Canal will be closed Monday for two hours. That’s where the 16th-century Cavalli Palace is located — leading many to believe Clooney and his bride will have a formal ceremony Saturday, and then a civil ceremony Monday.

With News Wire Services

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